paul, whilst all combi's work in pretty much the same way, I have to say that I don't find them all the same. there are some which stand above the rest in terms of build quality and reliability. i'm not going to list them here, but combi's like bikes, aren't all equal, though they all do roughly the same thing. also its worth mentioning that NOT all combi's will take a pre heated cold feed. the solution for those that wont is to use a thermostatic mixer valve on the hot feed AFTER the combi.
air source heat pumps, like ground source ones are touted as the future technology to watch, but im not convinced, they still require a reasonably large quantity of electricity to run them, despite their obvious efficiency advantages over gas heating, and the heat pump technology is pretty specialised stuff to maintain, you think plumbers are expensive, try calling an a/c guy out, that will really make you wince! i think its too young a technology to throw money at just yet. its getting there, but its still not quite up to the mark. i went to the worcester technology centre last year, and they were just running load tests on their greenskies ashp unit, and whilst it looked promising, its still not quite powerful enough.
finally, theres the water byelaws to take into account. if youre planning to run a cylinder in reverse like you say, then you will still need to be aware of the regulations governing unvented hot water systems, which is in fact what you will be making, and the possible legal pitfalls of such an installation. im not saying don't do it, but im just pointing out that the supply of water is quite strictly governed in the uk for a reason, and if you choose to break the rules, at least be aware of what they are. 'it was only in my own house so affects no one else' isnt an excuse that would stand up in court.